Carbon Tetrachloride having actually its chemical formula as CCl4 is an organic compound. It is a colorless liquid through a sweet smell. It is likewise toxic to the huguy body on its straight exposure. We will research the properties of CCl4 in information. Chemistry students may have actually doubts about whether CCl4 is polar or nonpolar. So, In this short article, I will certainly answer this question and also will certainly cover the bordering topics also.

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SO, Is CCl4 polar or nonpolar? CCl4 (Carbon tetrachloride) is nonpolar in nature. Although the 4 bonds C-Cl are polar because of the difference in electronegativity of Chlorine(3.16) and also Carbon(2.55), CCl4 is nonpolar because the bond polarity gets canceled via each various other because of the symmetrical geometrical structure (tetrahedral) of the CCl4 molecule.

Carbon Tetrachloride is an IUPAC name offered to CCl4 and also it exists as a liquid state at room temperature. It produces a sweet odor that have the right to be conveniently detected at reduced levels.

It was uncovered by Henri Victor Regnault in the year 1839.

CCl4 molecule has actually one carbon atoms attached to the 4 chlorine atom. All four bond C-Cl are similar as well as symmetrical to each various other.

It is vital to understand also that symmeattempt of a chemical compound is a really necessary factor in determining the polarity of a compound.

It can be construed bereason Carbon and also Chlorine atom have actually a various value of electronegativity ie (C= 2.55, Cl= 3.16). Making the C-CL bond a polar covalent bond.

Because of this all four C-Cl bonds have actually a dipole minute value also. But because of the symmetry of all four bonds, the dipole moment of the C-Cl bond gets canceled by the opposite C-Cl bond. As an outcome, the net dipole minute turns out to be zero making the CCl4 a nonpolar molecule.

Methane gas (CH4) does additionally has the very same framework as CCl4.

What are Polar and also Nonpolar Molecules?

It is to be provided that a molecule is considered to be polar if the net dipole moment of that molecule is zero. However, It is possible to have actually the presence of a polar bond within a nonpolar molecule.

As discussed above in CCl4, C-CL has some value of dipole minute and also is polar in nature however all at once CCl4 molecule is nonpolar in nature bereason the net dipole minute of CCl4 molecule is zero.

Polar molecule: These are the molecules that have some positive worth of net dipole moment. These molecules likewise have actually asymmetric geometrical structures. A chemical bond is shelp to be polar if the charges are not equally distributed over both atoms developing that bond. The electrons are not equally shared among both atoms.

In such chemical bonds, the electron pair gets slightly puburned in the direction of the more electronegative atom among both atoms. Due to the distinction in electronegativity and asymmetric geometry, these molecule becomes polar.

Non-Polar molecules: The molecules that have actually net dipole moment as zero is a nonpolar molecule. In these molecules, the geometrical structure is likewise symmetric.

Amongst 2 atoms creating a chemical bond, that bond is shelp to be polar if the charges are equally dispersed over both of them that indicates the electrons are equally common by both of the atoms.

Why CCl4 is Nonpolar?

The CCl4 is nonpolar in nature because of the symmetrical tetrahedral geometrical framework. Although the C-CL bond is polar in nature as Carbon and Chlorine atoms have a distinction in their electronegativity.

As an outcome, the C-Cl bond additionally has actually a dipole minute. But due to symmetrical framework, the net dipole minute gets canceled through each other forming CCl4 (Carbon Tetrachloride) a nonpolar molecule.

The polarity of a molecule depends upon the assorted factors debated below.

Factors affecting polarity of a compound

Electronegativity: in a chemical bond between two atoms, the bond is said to be polar if the two atoms have a difference in their electronegativity. Greater the difference of electronegativity of two atoms more is the polarity of that bond.

But it is very vital to know that molecule having actually polar bond within itself deserve to also be nonpolar bereason of its symmetrical structure. In such cases, the polarity of bonds canceled out with each various other.

Geometrical Structure: The molecule having actually its symmetrical geometrical shape is nonpolar in nature. The net dipole minute worth transforms out to be zero for symmetrical molecules.

Dipole moment: The molecules having net dipole moment are polar in nature whereas the molecules that have zero dipole minute are nonpolar in nature.

Geometrical Structure of CCl4

If we talk around the geometrical framework of tetrachloromethane, the four bonds C-Cl lie at symmetric orientations relative to other C-Cl bonds. The carbon atom is the main atom linked via four C-Cl bonds.

The carbon atom has actually 4 electrons in its outermany shell and also all 4 bonds get involved in the formation of covalent bonds created via four chlorine atoms leaving behind no lone pair on the carbon atom.

The CCl4 forms the tetrahedral geomeattempt and also the bond angle in the CCl4 molecule is roughly 109.5 levels.

Carbon tetrachloride develops sp3 hybridization via one s orbital and 3 p orbitals of Carbon.

All the non-bonding electrons in CCl4 has a tendency to create a repulsive force among each various other resulting in the bond angle of 109.5 degrees via each various other and resulting in a tetrahedral shape.

For comprehensive information about valence electrons and the lewis framework, you should go through the lewis framework, hybridization of CCl4.


Synthesis of CCl4

The formation of tetrachloromethane is done in the year 1839 by the French chemist Henri Victor Regnault. It was synthesized by reacting chloroform and chlorine.

But nowadays, the process of manufacturing tetrachloromethane is done by treating methane through chlorine. The reaction is given as below

CH4 (Methane) + 4Cl2 (chlorine) ———> CCl4 + 4 HCl (acid)

Before the 1950s, the procedure of manufacturing carbon tetrachloride was done by dealing with carbon disulfide via chlorine at 105 to 130 degrees Celcius.

CS2 (carbon disulphide) + 3Cl2 (Chlorine) ——-> CCl4 + S2Cl2

Physical and also Chemical properties of CCl4

CCl4 (Carbon Tetrachloride) exists as a liquid at room temperature.It exists as a colormuch less liquid and likewise provides a sweet smell.The melting suggest of Carbon Tetrachloride is about -23 levels Celcius.It has its boiling suggest around 76 levels Celcius.The geometrical form of Carbon Tetrachloride is symmetrical tetrahedral.The density of Carbon Tetrachloride is around 1.5867 g cm−3.CCl4 is soluble in chlorocreate, formic acid, alcohol, ether, CS2, naphtha, benzene.The vapor pressure of CCl4 is 11.94 kPa at 20 °C.CCl4 is toxic in nature and also it has actually ozone-depleting properties and also also classified as a greenhouse gas.

Uses of CCl4

The Tetra Chloromethane becomes an excellent solvent for many type of nonpolar substances bereason of its nonpolar nature.It is a great source of chlorine for the synthesis of chlorine-based organic compounds.It additionally has its excellent usage in NMR spectroscopy due to the lack of hydrogen atoms in the CCl4 molecule.Tetrachloromethane has its good usage in the fire extinguishers, it prevents the fire by extinguishing the flames of fire.


The molecule of CCl4 is nonpolar in nature bereason of its symmetrical tetrahedral framework. However the C-Cl bond is a polar covalent bond, but the 4 bonds cancel the polarity of each various other and develop a nonpolar CCl4 molecule.

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So, In this article, I tried to cover the nonpolar nature of Carbon Tetrachloride molecule(CCl4). If you males have any kind of questions concerning this, you deserve to ask that in the comment section below. We will certainly reach out to you as soon as feasible.