L>InClass02 Ksp 105F96InClass02 Ksp 105F96Chem 105 InClass job-related Answer SheetSolubility ProductSep 19, 1996Name ____________________________1.0.5143 g that Ag2CrO4 is inserted in 104.3 mL of water.Ksp of silver- chromate is 1.2x10-12.A.Write the dissociation reaction for silver- chromate, then compose theKsp expression for silver- chromate.

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Ag2CrO4 = 2Ag+ +CrO42-Ksp = 2 =1.2 x 10-12B.Calculate the concentration of Ag+ and also ofCrO42-.Since over there is no resource of silver or of chromate outside of the dissociationof silver- chromate itself, this is a straightforward solubility problem.From charge Balance = 2. Lets = ; then = 2s . Plugginginto the Ksp expression, (2s)2s = Ksp, or4s3 = Ksp, or s = (Ksp/4)1/3.Putting in the values:You might need to discover out exactly how to take the cube source on her calculator. Look uphow to usage the yx button. = 2s = 2(6.69 x 10-5) = 1.34 x 10-4.2.A solution known to have = 0.045 M has actually a pile of silverchromate in the bottom of it. Compute the concentration the chromate in the solution.Since the has actually been established by addition from the outside,probably as AgNO3, this is a common ion problem. From theKsp expression in trouble 1A above, we have:Note that if silver nitrate had been the source of the excess silver, and ifthe trouble had stated that CAg+ = 0.045 M then fee balance wouldbe: = 2 + would be large, 0.045 M, but chromate would bevery small, about5.9x10-10 M, for this reason = =0.045 M to a very an excellent approximation.

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3.100.0 mL of 0.100 M AgNO3 and also 50.0 mL of 0.300 M NaCl space mixedtogether. Complete the complying with Initial/Final Spreadsheet, finallycalculating the concentrations of all species in equipment after reaction hastaken place. Ksp AgCl is 1.82x10-10.Balanced Reaction: Ag+ + NO3- +Na+ + Cl- = AgCl(s) + Na+ +NO3-millimolesAg+millimolesNO3-millimolesNa+millimolesCl-millimolesAgCl(s)VolumesInitial10.0 mmoles10.0 mmoles15.0 mmoles15.0 mmolesnone yet100 +50 mLFinal~010.0 mmoles15.0 mmoles5.0 mmoles10.0 mmolesprecipitate150 mLMolarConc.5.47x10-9M0.0667 M0.100 M0.0333 Mnotin solutionInitial millimoles:Since AgNO3 ionizes totally in solution ("all nitrates aresoluble"),mmole Ag+ = mmoles NO3- = 100 mL x 0.100 mmoleAgNO3/mL = 10.0 mmole Ag+ andNO3-Since all sodium salts space soluble, NaCl ionizes completely in solution, sommole Na+ = mmole Cl- = 50 mL x 0.300 mmole NaCl/mL =15.0 mmole Na+ and also Cl- last millimoles:Silver is the limiting reagent, so it goes to roughly zero.Chloride is lessened from 15 mmoles to 5 mmoles after ~ the 1:1 reaction withsilver.10.0 mmoles the AgCl(s) are created as a precipitate that sits at the bottom ofthe beaker.The spectator ions stay unchanged.Final Molar Concentrations:CNO3- = 10.0 mmoles/150 mL = 0.0667 MCNa+ = 15.0 mmoles/150 mL = 0.100 MCCl- = 5.0 mmoles/150 mL = 0.0333 Mthen = Ksp/; appx. =Ksp/CCl- = 1.82x10-10/0.0333 =5.47x10-9 M (common ion problem) return to 105 residence Page